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How Chemical Bonds Drive Crystallisation and Crystal Growth

1How Bond Type Controls Crystal Nucleation and Growth
How Bond Type Controls Crystal Nucleation and Growth

Two Different Questions

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So we have two very different questions being answered at once. Lattice energy asks how stable the finished crystal is, and that is dominated by the strong bonds — covalent, ionic, and metallic.
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Lattice energy and crystal habit answer different questions. Lattice energy measures how stable the final bulk crystal is, and it is dominated by the strong bonds — covalent, ionic, and metallic. Habit is set by growth kinetics: which faces grow fastest during crystallisation, and that is controlled by the weak, short-range interactions at the surface. This is why a crystal can be held together overwhelmingly by strong bonds while its outward shape is decided by forces that contribute almost nothing to its stability.

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